WebDec 15, 2010 · The present invention relates to a preparation process for a phenylhydrazine hydrochloride. According to the process, a phenylhydrazine hydrochloride is adopted as a starting raw material, and is subjected to a diazotization reaction, a reduction reaction, and a hydrolysis reaction to prepare the phenylhydrazine hydrochloride, wherein the reduction … Phenylhydrazin ist selbstentzündlich, wenn es verunreinigt wird oder in Kontakt mit Stoffen mit großer Oberfläche (z. B. Putzwolle oder Sand) kommt. Seine Dämpfe können beim Erhitzen über seinen Flammpunkt (89 °C) mit Luft ein explosionsfähiges Gemisch bilden. Phenylhydrazin gilt als krebserzeugend, ist ein starkes Blutgift (Methämoglobinbildung) und verursacht auf der Haut Ekzeme. Darüber hinaus führt es zu einer irreversiblen Schädigung des Blutfarbstoffs und der Ery…
Einwirkung von Acetessigester auf Phenylhydrazin - Knorr - 1883 ...
Phenylhydrazine is used to prepare indoles by the Fischer indole synthesis, which are intermediates in the synthesis of various dyes and pharmaceuticals. Phenylhydrazine is used to form phenylhydrazones of natural mixtures of simple sugars in order to render the differing sugars easily separable from each other. This … See more Phenylhydrazine is the chemical compound with the formula C6H5NHNH2. It is often abbreviated as PhNHNH2. It is also found in edible mushrooms. See more Phenylhydrazine is prepared by oxidizing aniline with sodium nitrite in the presence of hydrogen chloride to form the diazonium salt, … See more Exposure to phenylhydrazine may cause contact dermatitis, hemolytic anemia, and liver damage. See more Phenylhydrazine forms monoclinic prisms that melt to an oil around room temperature which may turn yellow to dark red upon exposure to air. Phenylhydrazine is miscible with ethanol, diethyl ether, chloroform and benzene. It is sparingly soluble in water. See more Phenylhydrazine was the first hydrazine derivative characterized, reported by Hermann Emil Fischer in 1875. He prepared it by reduction of a phenyl diazonium salt using sulfite salts. Fischer used phenylhydrazine to characterize sugars via … See more • Phenylhydrazines at the U.S. National Library of Medicine Medical Subject Headings (MeSH) • PubChem See more WebCAS number: 100–63–0 NIOSH REL: 0.14 ppm (0.6 mg/m 3) 2-hr CEILING [skin]; NIOSH considers phenylhydrazine to be a potential occupational carcinogen as defined by the … one movie title
Phenylhydrazine MSDS - 107251 - Merck
Web2,4-Dinitrophenylhydrazine ( 2,4-DNPH or DNPH) is the organic compound C 6 H 3 (NO 2) 2 NHNH 2. DNPH is a red to orange solid. It is a substituted hydrazine. The solid is relatively … WebNIOSH. At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: (APF = 10,000) Any self-contained breathing apparatus that has a full … WebJun 20, 1996 · The present invention discloses a method for preparing phenylhydrazine hydrochloride, which is characterized in that hydrochloric acid and sodium nitrite are added to phenylamine in turn; the mole ratio of the henylamine to the hydrochloric acid to the sodium nitrite is 1: 2.3 to 3.2: 1 to 1.1, and the sodium nitrite is added at the temperature … one movies